Klepov Lab

Independent career at UGA

90. Valueva, A.D.; Novikov, S.A.; Bledsoe, J.; Cai, Y.; Maksimova, A.A.; Locklin, J.; Zhao, Y.; Klepov, V.; Cubic Halide Perovskites in the Cs(Pb_1-xSn_x)(Br_3-yCl_y) Solid Solutions for Crack-Free Bridgman Grown Single Crystals

MRS Comm. 2024 DOI: 10.1557/s43579-024-00535-6

Early Career Materials Researcher issue

89. Bledsoe, J.; Crane, G.; Drewke, J.; Klepov, V.; Locklin, J. Balancing Melt Solubility and Morphology in Epitaxial Nucleation: The Case of Nicotinic Acid and Poly(hydroxybutyrate-co-hydroxyhexanoate)

ACS Appl. Polym. Mater. 2023, 5 (10), 8600–8607. DOI: 10.1021/acsapm.3c01692

88. Novikov, S. A.; Casey, J.; Long, H. A.; Bledsoe, J. C.; Locklin, J. J.; Klepov, V. V.* Electron deficiency in 2D chalcogenide NaCu₄S₃ with metallic properties.

Cryst. Growth Des. 2023, 23 (10), 7243–7251. DOI: 10.1021/acs.cgd.3c00649

Prior to UGA

2023

87. Liu, Z.; Peters, J.; Bayikadi, K.; Klepov, V.; Pan, L.; Pandey, I.; Kanatzidis, M. G.; Wessels, B. Defects of perovskite semiconductor CsPbBr₃ investigated via photoluminescence and thermally stimulated current spectroscopies

J. Appl. Phys. 2023, 134, 245101. DOI: 10.1063/5.0177809

86. De Siena, M. C.#; Klepov, V. V.#; Stepanoff, S. P.; Bayikadi, K. S.; Pan, L.; Pandey, I. R.; Karki, S.; Chung, D. Y.; Wolfe, D. E.; Kanatzidis, M. G. Extreme γ‐Ray Radiation Tolerance of Spectrometer‐Grade CsPbBr₃ Perovskite Detectors.

Adv. Mater. 2023, 2303244. DOI: 10.1002/adma.202303244

85. Vasileiadou, E. S.; Tajuddin, I. S.; De Siena, M. C.; Klepov, V. V.; Kepenekian, M.; Volonakis, G.; Even, J.; Wojtas, L.; Spanopoulos, I.; Zhou, X.; Iyer, A. K.; Fenton, J. L.; Dichtel, W. R.; Kanatzidis, M. G. Novel 3D Cubic Topology in Hybrid Lead Halides with a Symmetric Aromatic Triammonium Exhibiting Water Stability.

Chem. Mater. 2023, 35 (14), 5267–5280. DOI: 10.1021/acs.chemmater.3c00164

84. Pan, L.; Liu, Z.; Welton, C.; Klepov, V. V.; Peters, J. A.; De Siena, M. C.; Benadia, A.; Pandey, I.; Miceli, A.; Chung, D. Y.; Reddy, G. N. M.; Wessels, B. W.; Kanatzidis, M. G. Ultrahigh‐Flux X‐ray Detection by a Solution‐Grown Perovskite CsPbBr₃ Single‐Crystal Semiconductor Detector.

Adv. Mater. 2023, 2211840. DOI: 10.1002/adma.202211840

83. Klepov, V. V.; De Siena, M. C.; Pandey, I. R.; Pan, L.; Bayikadi, K. S.; Butun, S.; Chung, D. Y.; Kanatzidis, M. G. Laser Scribing for Electrode Patterning of Perovskite Spectrometer-Grade CsPbBr₃ Gamma-Ray Detectors.

ACS Appl. Mater. Interfaces 2023, 15 (13), 16895–16901. DOI: 10.1021/acsami.3c01212

82. Berseneva, A. A.; Klepov, V. V.; Tisdale, H. B.; zur Loye, H.-C. Flux-Assisted Polytypism in the [Na₂Cl]GaQ₂ Heterolayered Salt-Inclusion Chalcogenide Family.

CrystEngComm 2023, 25 (15), 2307–2312. DOI: 10.1039/D3CE00074E

81. Liu, Z.; Peters, J. A.; Pan, L.; Klepov, V.; De Siena, M.; Benadia, A.; Chung, D. Y.; Kanatzidis, M. G.; Wessels, B. W. Investigation of Defects in Melt and Solution Grown Perovskite CsPbBr₃ Single Crystals.

Appl. Phys. Lett. 2023, 122 (13), 131902. DOI: 10.1063/5.0142802

80. Pan, L.; Pandey, I. R.; Miceli, A.; Klepov, V. V.; Chung, D. Y.; Kanatzidis, M. G. Perovskite CsPbBr₃ Single‐Crystal Detector Operating at 10¹⁰ Photons s^-1 mm^-2 for Ultra‐High Flux X‐ray Detection.

Adv. Opt. Mater. 2023, 2202946. DOI: 10.1002/adom.202202946

2022

79. Fu, P.; Quintero, M. A.; Welton, C.; Li, X.; Cucco, B.; De Siena, M. C.; Even, J.; Volonakis, G.; Kepenekian, M.; Liu, R.; Laing, C. C.; Klepov, V.; Liu, Y.; Dravid, V. P.; Manjunatha Reddy, G. N.; Li, C.; Kanatzidis, M. G. Short Aromatic Diammonium Ions Modulate Distortions in 2D Lead Bromide Perovskites for Tunable White-Light Emission.

Chem. Mater. 2022, 34 (21), 9685–9698. DOI: 10.1021/acs.chemmater.2c02471

78. Pan, L.; He, Y.; Klepov, V. V.; De Siena, M. C.; Kanatzidis, M. G. Perovskite CsPbBr₃ Single Crystal Detector for High Flux X-Ray Photon Counting.

IEEE Trans. Med. Imaging 2022, 41 (11), 3053–3061. DOI: 10.1109/TMI.2022.3176801

77. Vasileiadou, E. S.; Jiang, X.; Kepenekian, M.; Even, J.; De Siena, M. C.; Klepov, V. V.; Friedrich, D.; Spanopoulos, I.; Tu, Q.; Tajuddin, I. S.; Weiss, E. A.; Kanatzidis, M. G.* Thick-Layer Lead Iodide Perovskites with Bifunctional Organic Spacers Allylammonium and Iodopropylammonium Exhibiting Trap-State Emission.

J. Am. Chem. Soc. 2022. 144 (14) 6390-6409. DOI: 10.1021/jacs.2c00571

76. He, Y.; Hadar, I.; De Siena, M. C.; Klepov, V. V.; Pan, L.; Chung, D. Y.; Kanatzidis, M. G.* Sensitivity and Detection Limit of Spectroscopic‐Grade Perovskite CsPbBr₃ Crystal for Hard X‐Ray Detection.

Adv. Funct. Mater. 2022, 32 (24), 2112925. DOI: 10.1002/adfm.202112925

75. Berseneva, A. A.; Klepov, V. V.; Pal, K.; Seeley, K.; Koury, D.; Schaeperkoetter, J.; Wright, J. T.; Misture, S. T.; Kanatzidis, M. G.; Wolverton, C.; Gelis, A. V.; zur Loye, H.-C.* Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS₃ Family.

J. Am. Chem. Soc. 2022, 144 (30), 13773–13786. DOI: 10.1021/jacs.2c04783

74. Novikov, S. A.; Lu, Y.; Zhang, W.; Halasyamani, P. S.; Hariyani, S.; Brgoch, J.; Klepov, V. V.; zur Loye, H.-C.; Mozharivskyj, Y.* Phosphorescence in Mn⁴⁺-Doped R⁺/R²⁺ Germanates (R+ = Na⁺ or K⁺, R²⁺ = Sr²⁺).

Inorg. Chem. 2022, 61 (24), 9364–9374. DOI: 10.1021/acs.inorgchem.2c01364

73. Carone, D.; Klepov, V. V.; Misture, S. T.; Schaeperkoetter, J. C.; Jacobsohn, L. G.; Aziziha, M.; Schorne-Pinto, J.; Thomson, S. A. J.; Hines, A. T.; Besmann, T. M.; zur Loye, H.-C.* Luminescence and Scintillation in the Niobium Doped Oxyfluoride Rb₄Ge₅O₉F₆:Nb.

Inorganics 2022, 10 (6), 83. DOI: 10.3390/inorganics10060083

72. Kutahyali Aslani, C.; Klepov, V. V.; zur Loye, H.-C.* Hydrothermal Synthesis of new Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(IO₃)(SO₄) and Ln₂(IO₃)₃(SO₄)OH∙3H₂O (Ln = Sm, Eu, Dy).

Solid State Sci. 2022. 129, 106918. DOI: 10.1016/j.solidstatesciences.2022.106918

71. Keerthisinghe, N.; Chsritian, M.S.; Berseneva, A. A.; Morrison, G.; Klepov, V. V.; Smith M.D.; zur Loye, H.-C.* Investigation of Metastable Low Dimensional Halometallates.

Molecules. 2022. 27 (1), 280. DOI: 10.3390/molecules27010280

2021

70. Torma, A.; Li, W.; Zhang, H.; Tu, Q.; Klepov, V. V.; Brennan, M. C.; McCleese, C. L.; Krzyaniak, M. D.; Wasielewski, M. R.; Katan, C.; Even, J.; Holt, M. V.; Grusenmeyer, T. A.; Jiang, J.; Pachter, R.; Kanatzidis, M. G.; Blancon, J.-C.*; Mohite, A. D.* Interstitial nature of Mn²⁺ doping in 2D perovskites.

ACS Nano. 2021. 15 (12), 20550-20561. DOI: 10.1021/acsnano.1c09142

69. Peters, J. A.; Liu, Z.; Bulgin, O.; He, Y.; Klepov, V. V.; De Siena, M. C.; Kanatzidis, M. G.; Wessels, B. W.* Excitons in CsPbBr₃ Halide Perovskite.

J. Phys. Chem. Lett. 2021, 12 (38), 9301–9307. DOI: 10.1021/acs.jpclett.1c02397

68. Klepov, V. V.; Pace, K. A.; Berseneva, A. A.; Felder, J. B.; Calder, S.; Morrison, G.; Zhang, Q.; Kirkham, M. J.; Parker, D. S.; zur Loye, H.-C.* Chloride reduction of Mn³⁺ in the mild hydrothermal synthesis of a charge ordered defect pyrochlore, CsMn²⁺Mn³⁺F₆, a canted antiferromagnet with a hard ferromagnetic component.

J. Am. Chem. Soc. 2021, 143 (30), 11554-11567. DOI: 10.1021/jacs.1c04245

67. Keerthisinghe, N.; Berseneva, A. A.; Klepov, V. V.; Morrison, G.; zur Loye, H.-C.* A Geometrically Frustrated Family of M^IIM^IIIF₅(H₂O)₂ Mixed–Metal Fluorides with Complex Magnetic Interactions.

Inorg. Chem. 2021, 60 (18), 14318–14329. DOI: 10.1021/acs.inorgchem.1c01889

66. Christian, M. S.*; Pace, K. A.; Klepov, V. V.; Morrison, G.; zur Loye, H.-C.*; Besmann, T. M.* A Density-Functional Theory Structural Database for Discovery of Novel Actinide Waste Forms.

Cryst. Growth Des. 2021, 21 (9), 5100–5107. DOI: 10.1021/acs.cgd.1c00494

65. Kutahyali Aslani, C.; Klepov, V. V.; Aslani, M.; zur Loye, H.-C.* Hydrothermal Synthesis of new Iodates Ln₂(IO₃)₃(IO₄) (Ln=La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, Tb.

Cryst. Growth Des. 2021, 21 (8), 4707-4712. DOI: 10.1021/acs.cgd.1c00545

64. Pace, K. A.; Klepov, V. V.; Smith, M. D.; Williams, T.; Morrison, G.; Lauterbach, J. A.; Misture, S. T.; zur Loye, H.-C.* Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate.

Inorganics 2021, 9 (4), 25. DOI: 10.3390/inorganics9040025

63. Morrison, G.; Klepov, V. V.; zur Loye, H.-C.* Pentanary Cesium Titanyl/Titanate Silicate Oxyfluorides: Syntheses and Structures.

Solid State Sci. 2021, 118, 106664. DOI: 10.1016/j.solidstatesciences.2021.106664

62. Kutahyali Aslani, C.; Breton, L. B.; Klepov, V. V.; zur Loye, H.-C.* A Series of Rb₄Ln₂(P₂S₆)(PS₄)₂ (Ln = La, Ce, Pr, Nd, Sm, Gd) Rare Earth Thiophosphates with Two Distinct Thiophosphate Units [P^VS₄]^3- and [P^IV₂S₆]^4-.

Dalton Trans. 2021, 50, 1683-1689. DOI: 10.1039/D0DT03718D

61.* Pace, K. A.§; Klepov, V. V. §*; Berseneva, A. A.; zur Loye, H.-C.* Covalency in Actinide Compounds.

Chem. Eur. J. 2021, 27 (19), 5835–5841. DOI: 10.1002/chem.202004632

60. Klepov, V. V.; Kocevski, V.; Besmann, T. M.; zur Loye, H.-C.* Dimensional Reduction upon Calcium Incorporation in Cs_0.3(Ca_0.3Ln_0.7)PS₄ and Cs_0.5(Ca_0.5Ln_0.5)PS₄.

CrystEngComm 2021, 23, 831-840. DOI: 10.1039/D0CE01524E

59. Kutahyali Aslani, C.; Klepov, V. V.; zur Loye, H.-C.* Flux Crystal Growth of a New BaTa₂O₆ Polymorph, and of the Novel Tantalum Oxyfluoride Salt Inclusion Phase [Ba₃F]Ta₄O₁₂F: Flux Dependent Phase Formation.

J. Solid State Chem. 2021, 294, 121833. DOI: 10.1016/j.jssc.2020.121833

2020

58.* Breton, L. B.§; Klepov, V. V.§*; zur Loye, H.-C.* Facile Oxide to Chalcogenide Conversion for Actinides using the Boron-Chalcogen Mixture Method. (§equal contribution)

J. Am. Chem. Soc. 2020, 142 (33), 14365–14373. DOI: 10.1021/jacs.0c06483

57. Carone, D.; Usman, M.; Klepov, V. V.; Smith, M. D.; Kocevski, V.; Besmann, T. M.; zur Loye, H.-C.* New Germanate and Mixed Cobalt Germanate Salt Inclusion Materials: [(Rb₆F)(Rb₄F)][Ge₁₄O₃₂] and [(Rb₆F)(Rb_3.1Co_0.9F_0.96)][Co_3.8Ge_10.2O₃₀F₂].

CrystEngComm 2020, 22 (46), 8072–8080. DOI: 10.1039/D0CE01099E

56. Ejegbavwo, O. A.; Berseneva, A. A.; Martin, C. R.; Leith, G. A.; Pandey, S.; Brandt, A. J.; Park, K. C.; Mathur, A.; Farzandh, S.; Klepov, V. V.; Heiser, B. J.; Chandrashekhar, M.; Karakalos, S. G.; Smith, M. D.; Phillpot, S. R.; Garashchuk, S.; Chen, D. A.*; Shustova, N. B.* Heterometallic Multinuclear Nodes Directing MOF Electronic Behavior.

Chem. Sci. 2020, 11 (28), 7379–7389. DOI: 10.1039/D0SC03053H

55. Pace, K. A.; Klepov, V. V.; Deason, T. K.; Smith, M. D.; Ayer, G. B.; DiPrete, D. P.; Amoroso, J. W.; zur Loye, H.-C.* Expansion of the Na₃M^III(Ln/An)₆F₃₀ Series: Incorporation of Plutonium into a Highly Robust and Stable Framework.

Chem. Eur. J. 2020, 26, 12941–12944. DOI: 10.1002/chem.202002774

54. Ayer, G. B.; Klepov, V. V.; Smith, M. D.; Hu, M.; Yang, Z.; Martin, C. R.; Morrison, G.; zur Loye, H.-C.* BaWO₂F₄: A Mixed Anion X-ray Scintillator with Excellent Photoluminescence Quantum Efficiency.

Dalton Trans. 2020, 49, 10734–10739. DOI: 10.1039/D0DT02184A

53. Keerthisinghe, N.; Klepov, V. V.; Zhang, E.; Smith, M. D.; Egodawatte, S.; Foulger, S. H.; zur Loye, H.-C.* Hydrothermal Synthesis and Properties of MMF₅(H₂O)₇ (M = Co²⁺ and Ni²⁺, M = Mn³⁺, Ga³⁺, and In³⁺).

Solid State Sci. 2020, 108, 106374. DOI: 10.1016/j.solidstatesciences.2020.106374

52. Pace, K. A.; Klepov, V. V.; Christian, M. S.; Morrison, G.; Deason, T. K.; Kutahyali Aslani, C.; Besmann, T. M.; Diprete, D. P.; Amoroso, J. W.; zur Loye, H.-C.* Targeting Complex Plutonium Oxides by Combining Crystal Chemical Reasoning with Density-Functional Theory Calculations: The Quaternary Plutonium Oxide Cs₂PuSi₆O₁₅.

Chem. Commun. 2020, 56 (66), 9501–9504. DOI: 10.1039/D0CC02674C

51. Klepov, V. V.; Berseneva, A. A.; Pace, K. A.; Kocevski, V.; Sun, M.; Qiu, P.; Wang, H.; Chen, F.; Besmann, T. M.; zur Loye, H.-C.* NaGaS₂: An Elusive Layered Compound with Dynamic Water Absorption and Wide-Ranging Ion-Exchange Properties.

Angew. Chem. Int. Ed. 2020, 59 (27), 10836–10841. DOI: 10.1002/anie.202001203

50. Juillerat, C. A.; Klepov, V. V.; Smith, M. D.; zur Loye, H.-C.* Targeted Crystal Growth of Uranium Gallates Via the Systematic Exploration of the UF₄-GaPO₄-ACl (A = Cs, Rb) Phase Space.

CrystEngComm 2020, 22, 3020–3032. DOI: 10.1039/D0CE00343C

49.* Klepov, V. V.*; Juillerat, C. A.; Pace, K. A.; Morrison, G.; zur Loye, H.-C.* “Soft” Alkali Bromide and Iodide Fluxes for Crystal Growth.

Front. Chem. 2020, 8, 518. DOI: 10.3389/fchem.2020.00518

48. Ayer, G. B.; Klepov, V. V.; Pace, K. A.; zur Loye, H.-C.* Quaternary Cerium(IV) Containing Fluorides Exhibiting Ce₃F₁₆ Sheets and Ce₆F₃₀ Frameworks.

Dalton Trans. 2020, 49, 5998–5905. DOI: 10.1039/D0DT00616E

47. Pace, K. A.; Koch, R. J.; Smith, M. D.; Morrison, G.; Klepov, V. V.; Besmann, T. M.; Misture, S. T.; zur Loye, H.-C.* Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A₂(UO₂)B₂O₅ (A = Cs, Rb, K).

Inorg. Chem. 2020, 59 (9), 6449–6459. DOI: 10.1021/acs.inorgchem.0c00536

46. Juillerat, C. A.; Kocevski, V.; Klepov, V. V.; Amoroso, J. W.; Besmann, T. M.; zur Loye H.-C.* Structure and Stability of Alkali Gallates Structurally Reminiscent of Hollandite.

J. Am. Ceram. Soc. 2020, 103 (11), 6531–6542. DOI: 10.1111/jace.17327

45. Klepov, V. V.; Pace, K. A.; Breton, L. S.; Kocevski, V.; Besmann, T. M.; zur Loye, H.-C.* Nearly Identical but not Isotypic – Influence of the Lanthanide Contraction on Cs₂NaLn(PS₄)₂ (Ln = La–Nd, Sm, Gd–Ho).

Inorg. Chem. 2020, 59 (3), 1905–1916. DOI: 10.1021/acs.inorgchem.9b03200

44. Uhanov, A. S.; Klepov, V. V.; Vologzhanina, A. V.; Zubavichus, Y. V.; Savchenkov, A. V.*; Pushkin, D. V.; Serezhkina, L. B.; Serezhkin, V. N. New Itaconate-Containing Uranyl Complex Unit and Coordination Modes of Itaconate Ions.

Comptes Rendus. Chimie 2020, 23 (2), 117–126. DOI: DOI: 10.5802/crchim.8

43. Hao, Y.; Alekseev, E. V.*; Klepov, V. V.; Yu, N.* Two Structural Variations in Complex Sodium Thorium Arsenates.

Eur. J. Inorg. Chem. 2020, 2020 (33), 3187–3193. DOI: 10.1002/ejic.202000492

2019

42.* Chekhomova, O. A.; Klepov, V. V.*; Pushkin, D. V.; Alekseev, E. V.; Vologzhanina, A. V.; Serezhkina, L. B.; Serezhkin, V. N. Structural Features of Uranyl Acrylate Complexes with s-, p-, and d-Monovalent Metals.

Z. Krist. Cryst. Mater. 2019, 234 (4), 247–256. DOI: 10.1515/zkri-2018-2089

41. Carone, D.; Klepov, V. V.; Smith, M. D.; zur Loye, H.-C.* Flux Crystal Growth of Lanthanide Tungsten Oxychlorides, La_8.64W₆O_30.45Cl, Ce_8.64W_5.74O₃₀Cl, and Ln_8.33W₆O₃₀Cl (Ln = Pr, Nd): Structural Stability in the Presence of Extreme Cation and Anion Disorder.

Inorg. Chem. 2019, 58 (24), 16831–16837. DOI: 10.1021/acs.inorgchem.9b03015

40. Ayer, G. B.; Klepov, V. V.; Smith, M.; zur Loye, H.-C.* Mild Hydrothermal Synthesis of the Complex Hafnium Containing Fluorides Cs₂[M(H₂O)₆][Hf₂F₁₂] (M= Ni, Co, and Zn), CuHfF₆(H₂O)₄ and Cs₂Hf₃Mn₃F₂₀ Containing HfF₇ and HfF₆ Coordination Polyhedra.

Inorg. Chem. 2019, 58 (19), 13049–13057. DOI: 10.1021/acs.inorgchem.9b01958

39. Usman, M.; Smith, M.; Klepov, V. V.; zur Loye, H.-C.* One-Dimensional Quaternary and Penternary Alkali Rare Earth Thiophosphates Obtained via Alkali Halide Flux Crystal Growth.

Cryst. Growth Des. 2019, 19 (10), 5648–5657. DOI: 10.1021/acs.cgd.9b00637

38. Usman, M.; Smith, M. D.; Morrison G.; Klepov, V. V.; Zhang, W.; Halasyamani, P. S.; zur Loye, H.-C.* Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties.

Inorg. Chem. 2019, 58 (13), 8541–8550. DOI: 10.1021/acs.inorgchem.9b00849

37. Klepov, V. V.; Smith, M. D.; zur Loye, H.-C.* Targeted Synthesis of Uranium(IV) Thiosilicates.

Inorg. Chem. 2019, 58 (13), 8275–8278. DOI: 10.1021/acs.inorgchem.9b01307

36. Klepov, V. V.; Breton, L. S.; Pace, K. A.; Kocevski, V.; Besmann, T. M.; zur Loye, H.-C.* Size-Driven Stability of Lanthanide Thiophosphates Grown from an Iodide Flux.

Inorg. Chem. 2019, 58 (9), 6565–6573. DOI: 10.1021/acs.inorgchem.9b00806

35. Klepov, V. V.; Pace, K. A.; Calder, S.; Felder, J. B.; zur Loye, H.-C.* 3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials.

J. Am. Chem. Soc. 2019, 141 (9), 3838–3842. DOI: 10.1021/jacs.9b00345

34. Klepov, V. V.; Morrison, G.; zur Loye, H.-C.* Na_nMTh₆F₃₀: A Large Family of Quaternary Thorium Fluorides.

Cryst. Growth Des. 2019, 19 (2), 1347–1355. DOI: 10.1021/acs.cgd.8b01742

33. Klepov, V. V.§; Juillerat, C. A. §; Alekseev, E. V.; zur Loye, H.-C.* Overstepping Löwenstein’s Rule - A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties.

Inorg. Chem. 2019, 58 (1), 724–736. (§equal authorship) DOI: 10.1021/acs.inorgchem.8b02906

32. Juillerat, C. A. §; Klepov, V. V. §; Morrison, G.; Pace, K. A.; zur Loye, H.-C.* Flux Crystal Growth: A Versatile Technique to Reveal the Crystal Chemistry of Complex Uranium Oxides.

Dalton Trans. 2019, 48 (10), 3162–3181. (§equal authorship) DOI: 10.1039/C8DT04675A

31. Usman, M.; Morrison, G.; Klepov, V. V.; Smith, M. D.; zur Loye, H.-C.* Flux Crystal Growth, Structure, Magnetic and Optical Properties of a Family of Alkali Uranium(IV) Phosphates.

J. Solid State Chem. 2019, 270, 19–26. DOI: 10.1016/j.jssc.2018.10.033

30. Serezhkina, L. B.*; Grigoriev, M. S.; Klepov, V. V.; Shimin, N. A.; Serezhkin, V. N. Synthesis and Structure of Strontium and Barium Uranyl Methacrylates.

Crystallogr. Rep. 2019, 64 (2), 270–276. DOI: 10.1134/S1063774519020251

2018

29. Serezhkin, V. N.*; Savchenkov, A. V.; Klepov, V. V.; Stefanovich, S. Y.; Pushkin, D. V.; Serezhkina, L. B. Relationship between the Structure and Nonlinear Optical Properties of R[UO₂L₃] and R₃[UO₂L₃]₄ Crystals (L—Carboxylate Ion).

Russ. J. Inorg. Chem. 2018, 63 (5), 647–654. DOI: 10.1134/S0036023618050145

28. Klepov, V. V.; Serezhkina, L. B.*; Grigor’ev, M. S.; Ignatenko, E. O.; Serezhkin, V. N. Uranyl Methacrylate Complexes with Carbamide and Methylcarbamide: Synthesis and Structure.

Russ. J. Inorg. Chem. 2018, 63 (8), 1019–1025. DOI: 10.1134/S0036023618080119

27. Pace, K. A.; Klepov, V. V.; Morrison, G.; zur Loye, H.-C.* Moderate Supercritical Synthesis as a Facile Route to Mixed-Valent Uranium(IV,V) and (V,VI) Silicates.

Chem. Comm. 2018, 54 (98), 13794–13797. DOI: 10.1039/C8CC07789D

26. Klepov, V. V.; zur Loye, H.-C.* Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates.

Inorg. Chem. 2018, 57 (17), 11175–11183. DOI: 10.1021/acs.inorgchem.8b01733

25. Klepov, V. V.; Felder, J. B.; zur Loye, H.-C.* Synthetic Strategies for the Synthesis of Ternary Uranium(IV) and Thorium(IV) Fluorides.

Inorg. Chem. 2018, 57 (9), 5597–5606. DOI: 10.1021/acs.inorgchem.8b00570

24. Li, H.; Kegler, P.; Klepov, V. V.; Klinkenberg, M.; Bosbach, D.; Alekseev, E. V.* Comparison of Uranium(VI) and Thorium(IV) Silicates Synthesized via Mixed Fluxes Techniques.

Inorg. Chem. 2018, 57 (11), 6734–6745. DOI: 10.1021/acs.inorgchem.8b01072

23. Hao, Y.; Klepov, V. V.; Kegler, P.; Modolo, G.; Bosbach, D.; Albrecht-Schmitt, T. E.; Wang, S.; Alekseev, E. V.* Synthesis and Study of the First Zeolitic Uranium Borate.

Cryst. Growth Des. 2018, 18 (1), 498–505. DOI: 10.1021/acs.cgd.7b01487

Prior 2018

22. Yu, N.; Klepov, V. V.; Schlenz, H.; Bosbach, D.; Kowalski, P. M.; Li, Y.; Alekseev, E. V.* Cation-Dependent Structural Evolution in A₂Th(T^VO₄)₂ (A = Li, Na, K, Rb, Cs; T = P and As) Series.

Cryst. Growth Des. 2017, 17 (3), 1339–1346. DOI: 10.1021/acs.cgd.6b01741

21.* Klepov, V. V.*; Serezhkina, L. B.; Grigoriev, M. S.; Shimin, N. A.; Stefanovich, S. Y.; Serezhkin, V. N. Morphotropy in Alkaline Uranyl Methacrylate Complexes.

Polyhedron 2017, 133, 40–47. DOI: 10.1016/j.poly.2017.04.041

20.* Klepov, V. V.*; Vologzhanina, A. V.; Alekseev, E. V.; Pushkin, D. V.; Serezhkina, L. B.; Sergeeva, O. A.; Knyazev, A. V.; Serezhkin, V. N. Structural Diversity of Uranyl Acrylates.

CrystEngComm 2016, 18 (10), 1723–1731. DOI: 10.1039/C5CE01957E

19.* Klepov, V. V.*; Serezhkina, L. B.; Serezhkin, V. N.; Alekseev, E. V.* Synthesis and Crystal Structure Analysis of Uranyl Triple Acetates.

J. Solid State Chem. 2016, 244, 100–107. DOI: 10.1016/j.jssc.2016.09.019

18.* Klepov, V. V.*; Serezhkina, L. B.; Pushkin, D. V.; Alekseev, E. V.; Grigor’ev, M. S.; Sergeeva, O. A.; Shimin, N. A.; Serezhkin, V. N. Uranyl Complexes with (Meth)Acrylate Anions.

Eur. J. Inorg. Chem. 2016, 2016 (1), 118–125. DOI: 10.1002/ejic.201501035

17. Xiao, B.; Kegler, P.; Gesing, T. M.; Robben, L.; Blanca-Romero, A.; Kowalski, P. M.; Li, Y.; Klepov, V.; Bosbach, D.; Alekseev, E. V.* Giant Volume Change and Topological Gaps in Temperature- and Pressure-Induced Phase Transitions: Experimental and Computational Study of ThMo₂O₈.

Chem. Eur. J. 2016, 22 (3), 946–958. DOI: DOI: 10.1002/chem.201503839

16. Hao, Y.; Klepov, V. V.; Murphy, G. L.; Modolo, G.; Bosbach, D.; Albrecht-Schmitt, T. E.; Kennedy, B. J.; Wang, S.; Alekseev, E. V.* Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates. Cryst.

Growth Des. 2016, 16 (10), 5923–5931. DOI: 10.1021/acs.cgd.6b00978

15*. Yu, N.; Klepov, V. V.*; Neumeier, S.; Depmeier, W.; Bosbach, D.; Suleimanov, E. V.; Alekseev, E. V.* Further Insight into Uranium and Thorium Metaphosphate Chemistry and the Effect of Nd³⁺ Incorporation into Uranium(IV) Metaphosphate.

Eur. J. Inorg. Chem. 2015, 2015 (9), 1562–1568. DOI: 10.1002/ejic.201403098 DOI: 10.1134/S0036023612050129

14. Yu, N.; Kegler, P.; Klepov, V. V.; Dellen, J.; Schlenz, H.; Langer, E. M.; Bosbach, D.; Alekseev, E. V.* Influence of Extreme Conditions on the Formation and Structures of Caesium Uranium(VI) Arsenates.

Dalton Trans. 2015, 44 (47), 20735–20744. DOI: 10.1039/C5DT03842A

13. Serezhkina, L. B.*; Grigor’ev, M. S.; Shimin, N. A.; Klepov, V. V.; Serezhkin, V. N. First Uranyl Methacrylate Complexes: Synthesis and Structure.

Russ. J. Inorg. Chem. 2015, 60 (6), 672–683. DOI: 10.1134/S0036023615060121

12. Savchenkov, A. V.*; Klepov, V. V.; Vologzhanina, A. V.; Serezhkina, L. B.; Pushkin, D. V.; Serezhkin, V. N. Trinuclear {Sr[UO₂L₃]₂(H₂O)₄} and Pentanuclear {Sr[UO₂L₃]₄}^2- Uranyl Monocarboxylate Complexes (L - Acetate or n-Butyrate Ion).

CrystEngComm 2015, 17 (4), 740–746. DOI: 10.1039/C4CE02103G

11. Yu, N.; Klepov, V. V.; Villa, E. M.; Bosbach, D.; Suleimanov, E. V.; Depmeier, W.; Albrecht-Schmitt, T. E.*; Alekseev, E. V.* Topologically Identical, but Geometrically Isomeric Layers in Hydrous α-, β-Rb[UO₂(AsO₃OH)(AsO₂(OH)₂)]·H₂O and Anhydrous Rb[UO₂(AsO₃OH)(AsO₂(OH)₂)].

J. Solid State Chem. 2014, 215, 152–159. DOI: 10.1016/j.jssc.2014.03.017

10. Yu, N.; Klepov, V. V.; Modolo, G.; Bosbach, D.; Suleimanov, E. V.; Gesing, T. M.; Robben, L.; Alekseev, E. V.* Morphotropy and Temperature-Driven Polymorphism in A₂Th(AsO₄)₂ (A = Li, Na, K, Rb, Cs) Series.

Inorg. Chem. 2014, 53 (20), 11231–11241. DOI: 10.1021/ic5018246

9. Yu, N.; Klepov, V. V.; Kegler, P.; Bosbach, D.; Albrecht-Schmitt, T. E.*; Alekseev, E. V.* Th(As^III₄As^V₄O₁₈): A Mixed-Valent Oxoarsenic(III)/Arsenic(V) Actinide Compound Obtained under Extreme Conditions.

Inorg. Chem. 2014, 53 (16), 8194–8196. DOI: 10.1021/ic5013704

8.* Klepov, V. V.*; Serezhkina, L. B.; Vologzhanina, A. V.; Pushkin, D. V.; Sergeeva, O. A.; Stefanovich, S. Y.; Serezhkin, V. N. Tris(Acrylato)Uranylates as a Scaffold for NLO Materials.

Inorg. Chem. Comm. 2014, 46, 5–8. DOI: 10.1016/j.inoche.2014.04.024

7. Klepov, V. V.; Vologzhanina, A. V.; Serezhkina, L. B.*; Serezhkin, V. N. Synthesis, Structure, and Properties of [Be(H₂O)₄][UO₂(CH₃COO)₃]₂.

Radiochem. 2013, 55 (1), 36–40. DOI: 10.1134/S1066362213010074

6.* Klepov, V. V.*; Peresypkina, E. V.; Serezhkina, L. B.; Karasev, M. O.; Virovets, A. V.; Serezhkin, V. N. Crystal Structure of [M(H₂O)₆][UO₂(CH₃COO)₃]₂ (M = Mg²⁺, Co²⁺ and Zn²⁺).

Polyhedron 2013, 61, 137–142. DOI: 10.1016/j.poly.2013.05.048

5. Klepov, V. V.; Peresypkina, E. V.; Serezhkina, L. B.; Virovets, A. V.; Serezhkin, V. N.* Synthesis and Structure of [Cr₃O(CH₃COO)₆(H₂O)₃][UO₂(CH₃COO)₃]·3H₂O.

Russ. J. Inorg. Chem. 2012, 57 (10), 1341–1347. DOI: 10.1134/S0036023612050129

4. Serezhkina, L. B.*; Vologzhanina, A. V.; Klepov, V. V.; Serezhkin, V. N. Synthesis and X-Ray Diffraction Study of (Cs_0.5Ba_0.25)[UO₂(CH₃COO)₃] and Ba_0.5[UO₂(CH₃COO)₃].

Crystallog. Rep. 2011, 56 (2), 265–269. DOI: 10.1134/S1063774511010214

3.Serezhkina, L. B.*; Vologzhanina, A. V.; Klepov, V. V.; Serezhkin, V. N. Crystal Structure of PbUO₂(CH₃COO)₄(H₂O)₃.

Crystallogr. Rep. 2011, 56 (1), 132–135. DOI: 10.1134/S1063774510061100

2. Serezhkina, L. B.*; Vologzhanina, A. V.; Klepov, V. V.; Serezhkin, V. N. Crystal Structure of R[UO₂(CH₃COO)₃] (R = NH₄⁺, K⁺, or Cs⁺).

Crystallogr. Rep. 2010, 55 (5), 773–779. DOI: 10.1134/S1063774510050093

1. Serezhkina, L. B.*; Peresypkina, E. V.; Virovets, A. V.; Klepov, V. V. Synthesis and Structure of (Rb_0.50Ba_0.25)[UO₂(CH₃COO)₃].

Crystallogr. Rep. 2010, 55 (2), 221–223. DOI: 10.1134/S1063774510020094